If they are Military Desert Boots that you earned serving our country, you can wear them with a speedo and a top hat if you want to. Otherwise, don't even think about it.

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Uh, you guys know what desert boots look like, right?

J. Crew Desert Boots

Clark's

While these are much better with, say, a chino suit or a khakis/jacket combo, they're not akin to wearing Doc Martens with your navy blue pinstripe. I'd say anywhere suede Bucks, or a Chelsea boot are welcome, these will do, too.

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More importantly, would you wear a suede belt with a suit? If you're trying to make a statement, make the right one. Wear a full grain leather; it's the standard for a reason.

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Only in the desert.

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I wouldn't but I also don't wear white athletic sock with a suit either (I see this all the time).
I have several pairs of Clarks (Desert Boot and Desert Trek) and they are true casual shoes and would only work with a really casual suit.

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Not if you need to make a good impression or if it is for a business or formal look! It all depends on what kind of suit, how you wear it and what is the occasion...Obviously you can wear what ever you want but if it is a business or formal suit and you care for the impression it will make...that will not be a good choice! You can probably wear them with a casual linen suit a sport or polo shirt and no tie...that will be the most suit I will wear with these shoes...and if the shoes are already look worn and dirty I wouldn't even do that..
To me shoes are the MOST important item in your look, so you need to be careful. Read HERE for more about the importance of boots in creating a look

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You can wear suede shoes with a suit and you can wear chukka boots or chelsea boots with a suit. Yet somehow one plus one does not equal two.
You can wear desert boots with chinos and chinos with a jacket but that's about as close as you are going to get to suited.

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